CO2 emissions in selected countries in 1990 and 2011 (in million metric tons)*

  1990 2011
China** 2,244.1 9,111.81
United States 4,868.7 5,402.89
India 582.3 2,257.04
Russian Federation 2,178.8 1,679.88
Japan 1,064.4 1,176.51
Germany 950.4 740.94
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This statistic shows the carbon dioxide emissions from fuel combustion in 1990 and 2011 in selected countries. The United States emitted approximately 5.4 billion metric tons of carbon dioxide in 2011.

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You can find additional information about this statistic on statista.com
http://www.statista.com/statistics/270499/co2-emissions-in-selected-countries/